From Ocean Teacher Library
Conversion Formulas for Chemistry Measurement Units
Background
This set of tables consolidates numerous resources that were created to support various classes over the years, and it includes the useful efforts of our friends in the marine data management world.
Basic Metric Units
| Mass
|
- gram = g
- milligram = 10-3 g = mg
- microgram = 10-6 g = ug or μg (in OceanTeacher, for simplicity, the usual symbol for micro is u)
- One liter (see below) of pure water has a mass of approximately 1000 grams, depending on purity, temperature and pressure. One liter of seawater has a mass of approximately 1025 grams, depending on salinity, temperature and pressure.
|
| Length
|
- meter = m
- decimeter = 10-1 m = dm
- centimeter = 10-2 m = cm
|
| Volume
|
- liter = l = dm3
- milliliter = 10-3 l = ml = cm3
- cubic meter = m3 = 103 dm3 = 103 l
- The terms "liter" and "milliliter" are widely used, but the preferred units of volume are now the cubic decimeter, dm3, and the cubic centimeter, cm3.
|
Amount of Substance
| Mole
|
- Mole is usally abbreviated mol in unit designation
- Mole = 6.02 X 1023 molecules of a molecular substance, or atoms of an element, or ions of an ionic species in solution
- A mole is contained in the molecular weight or the atomic weight (as appropriate) of a substance, weight out in grams (see below for specific weights)
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| Sub-molar Quantities
|
- millimol = mmol = 10-3 mol = 6.02·1020 molecules, or atoms, or ions
- micromol = umol = 10-6 mol = 6.02·1017 molecules, or atoms, or ions
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| Older Units
|
- gram-molecular weight = mol of a molecular substance
- gram-atomic weight = mol of an element
- These terms were used in the older literature and should be avoided today.
|
Molar Mass
| Atoms
|
- Oxygen: 15.994 g/mol (designated MMO below)
- Phosphorus: 30.974 g/mol (designated MMP below)
- Silicon: 28.086 g/mol (designated MMSi below)
- Nitrogen: 14.0067 g/mol (designated MMN below)
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| Compounds
|
- Oxygen, as O2: 31.998 g/mol (designated MMO2 below)
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| Ionic Species
|
- Phosphate (PO4): 94.9716 g/mol (designated MMPO4 below)
- Silicate (SiO3): 76.0842 g/mol (designated MMSiO3 below)
- Nitrate (NO3): 61.9887 g/mol (designated MMNO3 below)
- Nitrite (NO2): 45.9947 g/mol (designated MMNO2 below)
|
Concentration of Substance
| Basic Conversions (all substances)
|
- [g/dm3] = [mol/dm3] · MMX
- [g/dm3] ~ [g/kg] · 1.025
- For more accuracy in the /dm3-to-/kg conversion, use the true seawater density instead of 1.025. See the note below on exact conversions.
|
| Phosphate [PO4]
|
- [ug/dm3] = [umol/dm3] · 94.9716
- [umol/dm3] = [ug/dm3] · 0.01053
|
|
Phosphate-Phosphorus
[PO4-P]
|
- [PO4-P] = [PO4]·MMP/MMPO4 = [PO4] · 0.3261
- [ug/dm3] = [umol/dm3] · 30.974
- [umol/dm3] = [ug/dm3] · 0.0322
- This quantity is usuallly calculated from the standard ionic phosphate concentration determined for non-digested seawater samples
|
| Total Phosphorus
|
- This quantity is calculated exactly as Phosphate-Phosphorus, above, except the sample has been completely digested before phosphate determination, insuring that particulate phosphate and non-ionic organic dissolved phosphate are included in the measurement.
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| Silicate [SiO3]
|
- [ug/dm3] = [umol/dm3] · 78.0842
- [umol/dm3] = [ug/dm3] · 0.01280
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| Silicate-Silicon [SiO3-Si]
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- [SiO3-Si] = [SiO3]·MMSi/MMSiO3 = [SiO3] · 0.3691
- [ug/dm3] = [umol/dm3] · 28.086
- [umol/dm3] = [ug/dm3] · 0.03560
|
| Nitrate [NO3]
|
- [ug/dm3] = [umol/dm3] · 61.9887
- [umol/dm3] = [ug/dm3] · 0.01613
|
| Nitrate-Nitrogen [NO3-N]
|
- [NO3-N] = NO3]·MMN/MMNO3 = [NO3] · 0.2259
- [ug/dm3] = [umol/dm3] · 14.0067
- [umol/dm3] = [ug/dm3] · 0.07139
|
| Nitrite [NO2]
|
- [ug/dm3] = [umol/dm3] · 45.9947 [umol/dm3] = [ug/dm3] · 0.02174
|
| Nitrite-Nitrogen [NO2-N]
|
- [NO2-N] = [NO2]· MMN/MMNO2= [NO2] · 0.3045 [ug/dm3] = [umol/dm3] · 14.0067
- [umol/dm3] = [ug/dm3] · 0.07139
|
| Chlorophyll
|
- [g/m3] = [ mg/l ] = [ mg/dm3]
- [mg/m3] = [ug/l] = [ug/dm3]
|
| Oxygen [O2]
|
- 1 mol = 22.391 dm3 = 22931 cm3 at standard temperature and pressure
- 1 ml = 1 cm3 = 1/22391 mol = 0.00004461 mol = 44.61 umol
- 1 mg = 22.931/31.998 ml = 0.700 ml = 0.700 cm3
- [umol] = [ml/l] · 44.61 = [cm3/dm3] · 44.61
- [cm3/dm3] = [ml/l] = [umol] · 0.02241
- [ml/l] = [cm3/dm3] = [mg/l] · 0.700 = [mg/dm3] · 0.700
- [mg/l] = [mg/dm3] = [ml/l] · 1.428 = [cm3/dm3] · 1.428
|
Miscellaneous
| Depth
|
- You can use the following equations to convert between depth in meters and pressure (p) in decibars:
- p! = (gravity! · depth! · (1.028 + 2.4 · depth! * 10-6))/10
- It gives answers correct to within 0.1% (Provided by Harry Dooley of ICESInternational Council for the Exploration of the Sea)
- If you need a quick, gross estimation of p, and can accept a larger error, then you can use the formula:
- p! = depth! · 1.007
- This assumes that the product 2.4 · depth! · 10-6 is negligible, which is certainly not true at great depths.
- See Physical Oceanographic Measurements for more detailed information.
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| Exact Conversions of /dm3 to /kg Concentrations
|
- Use the Johns-Hopkins Seawater Equation of State Calculator to find the in situ densities, then divide the /dm3 values by the densities to get the /kg values.[Open the HTML source of the Calculator to find the included Java code if you want to write your own spreadsheet or database macros to perform batch conversion.]
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| Temperature
|
- °F (Fahrenheit) temperature data can be converted to °C (Celsius) with the following formula:
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Subsections of this Article
No subsections available
Information about this article
Short title: Conversion Formulas
Description: none
Expertise level: beginner
Author: Murray.Brown
Approval status: approved
Approved by: Murray.Brown
Last change: 2009-8-4
Subsection of: Chemical Oceanographic Measurements
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